Heterostructures for Spintronics

Experiments at BESSY II show two mutually reinforcing quantum effects in graphene-cobalt-iridium heterostructures

Symbolic illustration of a graphene layer on a microchip. In combination with a heavy-metal thin film and ferromagnetic monolayers, graphene could enable spintronic devices. © Dall-E/arö

Spintronic devices work with spin textures caused by quantum-physical interactions. A Spanish-German collaboration has now studied graphene-cobalt-iridium heterostructures at BESSY II. The results show how two desired quantum-physical effects reinforce each other in these heterostructures. This could lead to new spintronic devices based on these materials.

Spintronics uses the spins of electrons to perform logic operations or store information. Ideally, spintronic devices could operate faster and more energy-efficiently than conventional semiconductor devices. However, it is still difficult to create and manipulate spin textures in materials.

Graphene for Spintronics

Graphene, a two-dimensional honeycomb structure build by carbon atoms, is considered an interesting candidate for spintronic applications. Graphene is typically deposited on a thin film of heavy metal. At the interface between graphene and heavy metal, a strong spin-orbit coupling develops, which gives rise to different quantum effects, including a spin-orbit splitting of energy levels (Rashba effect) and a canting in the alignment of spins (Dzyaloshinskii-Moriya interaction). Especially the spin canting effect is needed to stabilise vortex-like spin textures, known as skyrmions, which are particularly suitable for spintronics.

Plus Cobalt Monolayers

Now, however, a Spanish-German team has shown that these effects are significantly enhanced when a few monolayers of the ferromagnetic element cobalt are inserted between the graphene and the heavy metal (here: iridium). The samples were grown on insulating substrates which is a necessary prerequisite for the implementation of multifunctional spintronic devices exploiting these effects.

Interactions observed

‘At BESSY II, we have analysed the electronic structures at the interfaces between graphene, cobalt and iridium,’ says Dr. Jaime Sánchez-Barriga, a physicist at HZB. The most important finding: contrary to expectations, the graphene interacts not only with the cobalt, but also through the cobalt with the iridium. ‘The interaction between the graphene and the heavy metal iridium is mediated by the ferromagnetic cobalt layer,’ Sánchez-Barriga explains. The ferromagnetic layer enhances the splitting of the energy levels. ‘We can influence the spin-canting effect by the number of cobalt monolayers; three monolayers are best,’ says Sanchez-Barriga.

This result is supported not only by experimental data, but also by new calculations using density functional theory conducted at Forschungszentrum Jülich. The fact that both quantum effects influence and reinforce each other is new and unexpected.

SPIN-ARPES at BESSY II

‘We were only able to obtain these new insights because BESSY II offers extremely sensitive instruments for measuring photoemission with spin resolution (Spin-ARPES). This leads to the fortunate situation that we can determine the assumed origin of the spin canting, i. e., the Rashba-type spin-orbit splitting, very precisely, probably even more precisely than the spin canting itself.,’ emphasises Prof. Oliver Rader, who heads the “Spin and Topology in Quantum Materials” department at HZB. There are only a very few institutions worldwide that have instruments with these capabilities. The results show that graphene-based heterostructures have great potential for the next generation of spintronic devices.

Publication:

ACS Nano (2024): Rashba-like Spin Textures in Graphene Promoted by Ferromagnet-Mediated Electronic Hybridization with a Heavy Metal
Beatriz Muñiz Cano, Adrián Gudín, Jaime Sánchez-Barriga, Oliver Clark, Alberto Anadón, Jose Manuel Díez, Pablo Olleros-Rodríguez, Fernando Ajejas, Iciar Arnay, Matteo Jugovac, Julien Rault, Patrick Le Fèvre, François Bertran, Donya Mazhjoo, Gustav Bihlmayer, Oliver Rader, Stefan Blügel, Rodolfo Miranda, Julio Camarero, Miguel Angel Valbuena, and Paolo Perna
DOI: 10.1021/acsnano.4c02154

Contact:

Helmholtz-Zentrum Berlin für Materialien und Energie
Department Spin and Topology in Quantum Materials

Dr. Jaime Sánchez-Barriga
+49 30 8062-15695
Email

apl. Prof. Dr. Oliver Rader
+49 30 8062-12950
Email

Dr. Antonia Rötger
Press Officer
+49 30 8062-43733
Email

Press release HZB, 20 September 2024