A simpler way to inorganic perovskite solar cells

Annealing in ambient air does not have an adverse effect on the optoelectronic properties of the semiconductor film, but actually results in fewer defects

Under the scanning electron microscope, the CsPbI₃ layer (large blocks in the upper part of the image) on the FTO substrate looks almost exactly the same after annealing in ambient air as after annealing under controlled conditions. © HZB

Inorganic perovskite solar cells made of CsPbI₃ are stable over the long term and achieve good efficiencies. A team led by Prof. Antonio Abate has now analysed surfaces and interfaces of CsPbI₃ films, produced under different conditions, at BESSY II. The results show that annealing in ambient air does not have an adverse effect on the optoelectronic properties of the semiconductor film, but actually results in fewer defects. This could further simplify the mass production of inorganic perovskite solar cells.

Metal halide perovskites have optoelectronic properties that are ideally suited for photovoltaics and optoelectronics. When they were discovered in 2009, halide perovskites in solar cells achieved an efficiency of 3.9 per cent, which then increased extremely fast. Today, the best perovskite solar cells achieve efficiencies of more than 26 per cent. However, the best perovskite semiconductors contain organic cations such as methylammonium, which cannot tolerate high temperatures and humidity, so their long-term stability is still a challenge. However, methylammonium can be replaced by inorganic cations such as Cesium (Cs). Inorganic halide perovskites with the molecular formula CsPbX₃ (where X stands for a halide such as chloride, bromide and iodide) remain stable even at temperatures above 300 °C. CsPbI₃ has the best optical properties for photovoltaics (band gap ∼1.7 eV).

Production in glove boxes

Perovskite semiconductors are produced by spin coating or printing from a solution onto a substrate and are typically processed in glove boxes under a controlled atmosphere: There, the solvent is evaporated by heating, after which a thin layer of perovskite crystallizes. This 'controlled environment' significantly increases the cost and complexity of production.

…or ambient conditions

In fact, CsPbI₃ layers can also be annealed under ambient conditions without loss or even with an increase in efficiency of up to 19.8 %, which is even better than samples annealed under controlled conditions.

What happens at the interfaces?

“We investigated the interfaces between CsPbI₃ and the adjacent material in detail using a range of methods, from scanning electron microscopy to photoluminescence techniques and photoemission spectroscopy at BESSY II,” says Dr. Zafar Iqbal, first author and postdoctoral researcher in Antonio Abate's team.

BESSY II unveils a surface modification

At BESSY II, the team of Prof. Marcus Bär used hard X-ray photoelectron spectroscopy (HAXPES) to analyse the chemical and electronic structure of the differently annealed CsPbI₃ and perovskite/hole transport layer interfaces. “In the samples that were annealed in ambient air, we observed a surface modification that improves the mobility of the charge carriers at the interface,” explains Iqbal. Optical spectroscopy showed that annealing in air resulted in fewer defects.

Upscaling might become simpler

“Our study explains why the annealing of CsPbI₃ films in ambient air works well,” says Iqbal. This could be particularly interesting for upscaling processes for potential mass production.

Note: Zafar Iqbal was financed by a fellowship by Deutscher Akademischer Austauschdienst (DAAD) during his PhD in the Abate Group.

Publication:

J. Am. Chem. Soc. (2024): Unveiling the Potential of Ambient Air Annealing for Highly Efficient Inorganic CsPbI₃ Perovskite Solar Cells
Zafar Iqbal, Roberto Félix, Artem Musiienko, Jarla Thiesbrummel, Hans Köbler, Emilio Gutierrez-Partida, Thomas W. Gries, Elif Hüsam, Ahmed Saleh, Regan G. Wilks, Jiahuan Zhang, Martin Stolterfoht, Dieter Neher, Steve Albrecht, Marcus Bär, Antonio Abate, and Qiong Wang
DOI: 10.1021/jacs.3c11711

Contact:

Helmholtz-Zentrum Berlin für Materialien und Energie

Zafar Iqbal
Active Materials and Interfaces for Stable Perovskite Solar Cells
+49 30 8062-17205
zafar.iqbal(at)helmholtz-berlin.de

Dr. Antonia Rötger
Press Officer
+49 30 8062-43733
antonia.roetger(at)helmholtz-berlin.de

Press release HZB, 17 April 2024